Basic device validates CNTs as potential successors to silicon semiconductors

A team of Stanford engineers has built a basic computer using carbon nanotubes, a semiconductor material that has the potential to launch a new generation of electronic devices that run faster, while using less energy, than those made from silicon chips.

This unprecedented feat culminates years of efforts by scientists around the world to harness this promising material.

The achievement is reported today in an article on the cover of NatureMagazine written by Max Shulaker and other doctoral students in electrical engineering. The research was led by Stanford professors Subhasish Mitra and H.S. Philip Wong.

"People have been talking about a new era of carbon nanotube electronics moving beyond silicon," said Mitra, an electrical engineer and computer scientist, and the Chambers Faculty Scholar of Engineering. "But there have been few demonstrations of complete digital systems using this exciting technology. Here is the proof."

Experts say the Stanford achievement will galvanize efforts to find successors to silicon chips, which could soon encounter physical limits that might prevent them from delivering smaller, faster, cheaper electronic devices.

"Carbon nanotubes (CNTs) have long been considered as a potential successor to the silicon transistor," said Professor Jan Rabaey, a world expert on electronic circuits and systems at UC Berkeley.

But until now it hasn't been clear that CNTs could fulfill those expectations.

"There is no question that this will get the attention of researchers in the semiconductor community and entice them to explore how this technology can lead to smaller, more energy-efficient processors in the next decade," Rabaey said.

Mihail Roco, senior advisor for Nanotechnology at the National Science Foundation, called the Stanford work "an important, scientific breakthrough."

It was roughly 15 years ago that carbon nanotubes were first fashioned into transistors, the on-off switches at the heart of digital electronic systems.

But a bedeviling array of imperfections in these carbon nanotubes has long frustrated efforts to build complex circuits using CNTs. Professor Giovanni De Micheli, director of the Institute of Electrical Engineering at École Polytechnique Fédérale de Lausanne in Switzerland, highlighted two key contributions the Stanford team has made to this worldwide effort.

"First, they put in place a process for fabricating CNT-based circuits," De Micheli said. "Second, they built a simple but effective circuit that shows that computation is doable using CNTs."

As Mitra said: "It's not just about the CNT computer. It's about a change in directions that shows you can build something real using nanotechnologies that move beyond silicon and its cousins."

Why worry about a successor to silicon? Such concerns arise from the demands that designers place upon semiconductors and their fundamental workhorse unit, those on-off switches known as transistors.

For decades, progress in electronics has meant shrinking the size of each transistor to pack more transistors on a chip. But as transistors become tinier they waste more power and generate more heat – all in a smaller and smaller space, as evidenced by the warmth emanating from the bottom of a laptop.

Many researchers believe that this power-wasting phenomenon could spell the end of Moore's Law, named for Intel Corp. co-founder Gordon Moore, who predicted in 1965 that the density of transistors would double roughly every two years, leading to smaller, faster and, as it turned out, cheaper electronics.

But smaller, faster and cheaper has also meant smaller, faster and hotter.

"Energy dissipation of silicon-based systems has been a major concern," said Anantha Chandrakasan, head of electrical engineering and computer science at MIT and a world leader in chip research. He called the Stanford work "a major benchmark" in moving CNTs toward practical use. CNTs are long chains of carbon atoms that are extremely efficient at conducting and controlling electricity. They are so thin – thousands of CNTs could fit side by side in a human hair – that it takes very little energy to switch them off, according to Wong, co-author of the paper and the Williard R. and Inez Kerr Bell Professor at Stanford.

"Think of it as stepping on a garden hose," Wong said. "The thinner the hose, the easier it is to shut off the flow." In theory, this combination of efficient conductivity and low-power switching make carbon nanotubes excellent candidates to serve as electronic transistors.

"CNTs could take us at least an order of magnitude in performance beyond where you can project silicon could take us," Wong said. But inherent imperfections have stood in the way of putting this promising material to practical use.

First, CNTs do not necessarily grow in neat parallel lines, as chipmakers would like.

Over time, researchers have devised tricks to grow 99.5 percent of CNTs in straight lines. But with billions of nanotubes on a chip, even a tiny degree of misaligned tubes could cause errors, so that problem remained.

A second type of imperfection has also stymied CNT technology.

Depending on how the CNTs grow, a fraction of these carbon nanotubes can end up behaving like metallic wires that always conduct electricity, instead of acting like semiconductors that can be switched off.

Since mass production is the eventual goal, researchers had to find ways to deal with misaligned and/or metallic CNTs without having to hunt for them like needles in a haystack.

"We needed a way to design circuits without having to look for imperfections or even know where they were," Mitra said. The Stanford paper describes a two-pronged approach that the authors call an "imperfection-immune design."

To eliminate the wire-like or metallic nanotubes, the Stanford team switched off all the good CNTs. Then they pumped the semiconductor circuit full of electricity. All of that electricity concentrated in the metallic nanotubes, which grew so hot that they burned up and literally vaporized into tiny puffs of carbon dioxide. This sophisticated technique was able to eliminate virtually all of the metallic CNTs in the circuit at once.

Bypassing the misaligned nanotubes required even greater subtlety.

So the Stanford researchers created a powerful algorithm that maps out a circuit layout that is guaranteed to work no matter whether or where CNTs might be askew.

"This 'imperfections-immune design' (technique) makes this discovery truly exemplary," said Sankar Basu, a program director at the National Science Foundation.

The Stanford team used this imperfection-immune design to assemble a basic computer with 178 transistors, a limit imposed by the fact that they used the university's chip-making facilities rather than an industrial fabrication process.

Their CNT computer performed tasks such as counting and number sorting. It runs a basic operating system that allows it to swap between these processes. In a demonstration of its potential, the researchers also showed that the CNT computer could run MIPS, a commercial instruction set developed in the early 1980s by then Stanford engineering professor and now university President John Hennessy.

Though it could take years to mature, the Stanford approach points toward the possibility of industrial-scale production of carbon nanotube semiconductors, according to Naresh Shanbhag, a professor at the University of Illinois at Urbana-Champaign and director of SONIC, a consortium of next-generation chip design research.

"The Wong/Mitra paper demonstrates the promise of CNTs in designing complex computing systems," Shanbhag said, adding that this "will motivate researchers elsewhere" toward greater efforts in chip design beyond silicon.

"These are initial necessary steps in taking carbon nanotubes from the chemistry lab to a real environment," said Supratik Guha, director of physical sciences for IBM's Thomas J. Watson Research Center and a world leader in CNT research.