A research team from the Department of Physics, The University of Hong Kong (HKU), discovered clear evidence to characterize a highly entangled quantum matter—the quantum spin liquid (QSL) (a phase of matter that remains disordered even at shallow temperatures) from large-scale simulations on supercomputers. This pivotal research work has recently been published in one of the leading journals in quantum materials—npj quantum materials. 

QSLs were proposed by P. W. Anderson—the Nobel Physics Laureate of 1977—in 1973, which had the potential to be used in topological quantum computing to bring the computing power of computers to a new stage and to help understand the mechanism of high-temperature superconductors, that could greatly reduce the energy cost during electricity transport owing to the absence of electrical resistance in superconductors.  

The QSL is termed a liquid due to its lack of conventional order in the matter. QSLs have a topological order that originates from long-range and strong quantum entanglement, while the detection of this topological order is a very tough task due to the lack of materials that can perfectly achieve the many model systems that scientists propose to find a topological order of QSL and prove its existence. Thus, there has not been concrete evidence that QSLs exist in nature.

Under this context, Mr. Jiarui ZHAO, Dr. Bin-Bin CHEN, Dr. Zheng YAN, and Dr. Zi Yang MENG from HKU Department of Physics, successfully probed this topological order in a phase of the Kagome lattice quantum spin model, which is a two-dimensional lattice model with intrinsic quantum entanglement and proposed by scientists that have Z2 (a cyclic group of order 2) topological order, via a carefully designed numerical experiment on supercomputers. Their unambiguous results of topological entanglement entropy strongly suggest the existence of QSLs in highly entanglement quantum models from a numerical perspective.

‘Our work takes advantage of the superior computing power of modern supercomputers, and we use them to simulate a very complicated model which is thought to possess topological order. With our findings, physicists are more confident that QSLs should exist in nature,’ said Mr. Jiarui Zhao, the first author of the journal paper and a Ph.D. student at the Department of Physics.

"Numerical simulations have been an important trend in scientific research of quantum materials. Our algorithms and computations could find more interesting and novel quantum matter and such efforts will surely contribute to the development of both practical quantum technology and the new paradigm in fundamental research." Dr. Zi Yang Meng, Associate Professor in the Department of Physics remarked.

The research
The team designed a numerical experiment on the Kagome spin model (Kagome is a two-dimensional lattice structure that shows a similar pattern to a  traditional Japanese woven bamboo pattern in the shape of hexagonal latticework) in the proposed QSL phase, and the schematic plot of the experiment is illustrated in Figure 2. The entanglement entropy (S) of a system can be obtained by measuring the change of the free energy of the model during a carefully designed nonequilibrium process. The topological entropy (γ), which characterizes long-range topological order, can be extracted by subtracting the short-range contribution, which is proportional to the length of the entanglement boundary (l) from the total entanglement entropy(S), by fitting the data of entanglement entropy of different entanglement boundary length to a straight line (S=al-γ).

The team experimented on two kinds of lattices with different ratios of length and width to ensure the reliability of the results. We use a straight line to fit the relation between the entanglement entropy with the length of the entanglement boundary so that the topological entropy should equal the intercept of the straight line. Our results give the value of topological entropy to be 1.4(2), which is consistent with the predicted value of topological entropy of a Z2 quantum spin liquid, which is 2ln (2). Our findings confirm the existence of QSLs from a numerical perspective.